By Douglas C. Neckers
Greater than an easy survey of the present literature, Advances in Photochemistry deals serious reviews written through the world over famous specialists. those pioneering scientists provide detailed and sundry issues of view of the present facts. Their articles are difficult in addition to provocative and are meant to stimulate dialogue, advertise extra learn, and inspire new advancements within the box.
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Extra resources for Advances in Photochemistry, Vol 27
Abraham, Phys. Rev. Lett. 1998, 81, 4628. 14. S. D. Cox, T. E. Gier, G. D. Stucky, and J. Bierlein, J. Am. Chem. Soc. 1988, 110, 2986. 15. L. Werner, J. Caro, G. Finger, and J. Kornatowski, Zeolites, 1992, 12, 658. 16. G. Schulz-Ekloff, in Advanced Zeolite Science and Applications, Studies in Surface Science and Catalysis, J. C. Jansen, M. Sto¨cker, H. G. Karge, and J. , Elsevier; Amsterdam, 1994, Vol. 85, p. 145. 17. M. Ehrl, F. W. Deeg, C. Bra¨uchle, O. Franke, A. Sobbi, G. Schulz-Ekloff, and D.
U. 25. Absorption and ﬂuorescence spectra of Pyþ and Oxþ in zeolite L, measured in an aqueous dispersion. The different spectral overlap regions are shaded. by the extinction coefﬁcient ej ð" v Þ of the acceptor as a function of the wave number v" (it is usually expressed in units of cm3/M). 25. It is difﬁcult to measure the oscillator strengths of molecules embedded in a matrix. Despite this, good values of Jij can be determined as a function of the temperature. A procedure we have used to extract the information from excitation spectra was to set the maximum of the excitation spectrum measured at room temperature equal to the extinction coefﬁcient at the absorption maximum in solution.
30. Diffusion of dye molecules in the channels of zeolite L. Idealized initial state of a channel and state after diffusion has occurred for some time. L channels. 30, at the beginning of the experiment. Immediately after all dye molecules have entered the zeolite channels, the maximum energy transfer is observed because the donor-to-acceptor distance is short. The donor-toacceptor distance increases, and hence the energy-transfer rate decreases, when the molecules diffuse deeper into the channels.
Advances in Photochemistry, Vol 27 by Douglas C. Neckers