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By Jane D. Anastassopoulou (auth.), E. Rizzarelli, T. Theophanides (eds.)

ISBN-10: 9401056064

ISBN-13: 9789401056069

ISBN-10: 9401136203

ISBN-13: 9789401136204

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500 . 000 H-I-I IV J. ooQ• . J -10 70 Dose ( 110 1SO 1;0 Gy) Figure 2. Gibbs Free Energy (~Gs) at 30°C for DNA samples exposed to y-rays for two Inverse Gas Chromatography probes bond hydrogen (n-Heptane and Toluene), participating in formation. K. LOUKAKIS ET AL. 023 g of DNA). 4. 1 FREE ENERGY Free energy indica~es the sorption propensity of a solute by a polymer and it lS a criterion of whether the process is spontaneous (negative ~Gs) or non spontaneous (positive ~Gs)· The free energy of sorption, ~Gs, was calculated directly from Vg 00 via eq.

20 V. BENHAM ET AL. Table I. Infrared assignments for pyrimidine complexes of copper, platinum and silver in the 1800-1500 cm- 1 region proposed assignments ([9] and this work) compound bands cm- 1 1,3-dimethyluracil 1710 1653 C(2)=0 C(4)=0 Cu{1,3-dimethyluracil) 2 1715 1652,1639 1598 C{2)=0 + ring C(4)=0 + ring ring 1-methyluracil 1697 1667 1620 C(2)=0 C( 4)=0 C(5)=C(6) cis- [ Pt ( NH 3 ) 2 ( 1-methyluraci 1)2 ]2H 20 1694 1659 1564 C(2)=0 C(4)=0 ring cis- [ ( NHJlt ( 1-methyluracil) 2 Cu(H20) 2 ]S04 • 4.

Am. Chern. , 112, 1255-1256 (1990). - Collet, A. Tetrahedron, 24, 5725-5759 (1987). Phenomena and Molecular Recognition, 44 A. ARDUINI ET AL. T. C. J. Am. Chern. , 111, 3075-3079 (1989). B. and Diederich, F. J. Am. Chern. , 112, 339-343 (1990). - Diederich, F. Angew. Chern. Int. Ed. , 27, 362-386 (1988). J. Science, 219, 1177-1183 (1983). W. J. Am. Chem. C. and Cram, D. J . J . C hem . Soc . ; Vincenti, M. J. J. Chem. Soc. Chern. Commun, 1403-1405 (1990). - Chang, K. and Cho, I. J. Chem. Soc. Perkin Trans.

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Chemistry and Properties of Biomolecular Systems by Jane D. Anastassopoulou (auth.), E. Rizzarelli, T. Theophanides (eds.)


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